Bis(ethanol-κO)bis(pyridine-3-carbaldehyde-κNthiosemicarbazone)bis(thiocyanato-κN)iron(II)–pyridine-3-carbaldehyde thiosemicarbazone (1/2)

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2-Chloro­quinoline-3-carbaldehyde

The quinolinyl fused ring system of the title compound, C(10)H(6)ClNO, is planar (r.m.s. deviation = 0.018 Å); the formyl group is slightly bent out of the plane of the fused ring system [C-C-C-O torsion angle = 8.2 (3)°].

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1H-Indole-3-carbaldehyde

In the title compound, C(9)H(7)NO, the benzene ring forms a dihedral angle of 3.98 (12)° with the pyrrole ring. In the crystal, N-H⋯O hydrogen bonds links the mol-ecules into chains which run parallel to [02-1].

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2-Meth­oxy­quinoline-3-carbaldehyde

In the title compound, C(11)H(9)NO(2), the quinoline ring system is essentially planar (r.m.s. deviation = 0.005 Å) and the meth-oxy and aldehyde groups are almost coplanar with it [N-C-O-C = 6.24 (19) and O-C-C-C = 0.3 (2)°]. In the crystal, mol-ecules are linked by pairs of C-H⋯O hydrogen bonds, forming centrosymmetric R(2) (2)(10) dimers. The dimers are linked via π-π inter-actions involving...

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The molecule of the title compound, C(18)H(14)N(4), lies on a center of inversion such that there is one half-mol-ecule in the asymmetric unit. The N-N single bond adopts a trans configuration and the indole fused-ring system is nearly coplanar with the -CH=N-N=CH- fragment [dihedral angle = 9.8 (2)°]. Adjacent mol-ecules are linked by indole-azine N-H⋯N hydrogen bonds into a layer motif.

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1H-Indole-3-carbaldehyde thio­semi­carbazone

The mol-ecules of the title compound, C(10)H(10)N(4)S, are linked by N-H(indole)⋯S hydrogen bonds to form a linear hydrogen-bonded chain. There are two independent mol-ecules in the asymmetric unit.

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ژورنال

عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online

سال: 2009

ISSN: 1600-5368

DOI: 10.1107/s1600536809024076